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Chemistry

How Does Nuclear Magnetic Resonance Distinguish Between Cis and Trans Alkenes?

Quick fact

In simple alkenes, the vinylic protons in cis isomers typically appear at a higher chemical shift (around 6-7 ppm) than those in trans isomers (around 5.5-6 ppm).

Why this is interesting

We know cis and trans alkenes are different, but how does a chemist tell them apart using just a magnet? NMR spectroscopy holds the answer—and it's all about which side the protons are on.