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Chemistry

The Impact of Isotopic Substitution on Reaction Rates

Quick fact

Deuterium, an isotope of hydrogen, has twice the mass of ordinary hydrogen. When a C–H bond is replaced by a C–D bond, the reaction can slow down by a factor of 6 to 10 or more—a dramatic change that helps chemists map out reaction pathways.

Why this is interesting

Imagine two identical molecules, except one contains a carbon atom twice as heavy as the other—yet the heavy one reacts slower. Why would a simple mass change affect how fast a chemical bond breaks?