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Chemistry

Methods for Determining Rate Laws Experimentally

Quick fact

The initial rates method can determine reaction orders without needing to fit complex curves: just measure the slope of concentration vs. time at the very start for several different starting concentrations.

Why this is interesting

How do chemists figure out that a reaction’s rate depends on, say, the square of the concentration of one reactant and not at all on another? The answer lies in clever experimental methods that reveal the hidden mathematical structure of chemical change.