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Chemistry

The Chemistry of Beta-Lactams and Their Mechanism of Inhibiting Transpeptidases

Quick fact

Beta-lactam antibiotics work by mimicking the natural substrate of transpeptidase enzymes—the D-alanyl-D-alanine end of peptidoglycan strands—and then forming a covalent bond that permanently blocks the enzyme's active site.

Why this is interesting

You've probably taken penicillin, but have you ever wondered how a simple molecule can stop a bacterial infection? The secret lies in a strained ring that tricks a key enzyme into a fatal embrace.